The best and easiest way to achieve exactly what you’re describing is to use a custom action to fill the the slot.
Why do you want to have a slot set to a json though? There might be another way for rasa to achieve your end goal without having a user enter actual code.
I don’t think ner_crf is the right extractor for extracting JSON out of your input. You will need to write your own extractor. Although, like @imLew said, there’s probably a better way for user to give this information.
You will have to write the extraction logic on your own. Here’s the documentation of how to create an NLU component that you can embed this logic into. Custom NLU Components